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For a metal to be more reactive means
that the metal will form its stable ion very easily
- by contributing 1 or more electrons to anything other non-metallic
element or ion it comes into contact with. Hence potassium atoms
form potassium ions easier than sodium atoms do. Potassium ion
also is more stable than sodium ion, which in turn is more stable
than calcium ion and so on.
To be more reactive also means that once the
metal ion is formed, it is difficult to put electrons back into
the stable ion to form back the elemental metal again. Hence,
it is therefore, very difficult to make sodium metal out of its
salt, sodium chloride. It requires an electrical method (by the
process of Down's Cell) to obtain sodium metal. However it is
much easier to obtain metallic iron, reducing iron ion back into
its metallic form. This is done by a chemical method, as in the
Blast Furnace Process - using only a chemical reducing agent (carbon
monoxide).
If a more reactive metal like iron is put into
contact with copper ions present in copper sulphate solution,
the former will donate 2 electrons per atom to copper ion, displacing
the latter out as metallic copper. Hence, we say that iron is
more reactive than copper.
In the series of photographs shown below, metallic
grey iron filings are able to displace copper out of blue
copper sulphate solution and visible changes are very noticeable.
The following changes are observed:
- Blue coloration of copper ions
(Cu2+) disappears
- Red brown copper metal appears
at the top of the grey iron filings
- Light green coloration of iron (II)
ions (Fe2+) is
seen
The net ionic equation is:
|
Cu2+(aq)
|
+
|
Fe0(s)
|
|
Cu0(s)
|
+
|
Fe2+(aq)
|
|
Blue solution
|
|
Grey powder
|
|
Reddish
brown metal
|
|
Light green solution |
Basically what the iron atom did was to contribute 2 electrons
(xx)per atom to the copper ion and let the latter ion come out
as red brown copper metal.
|
Cu2+(aq)
|
+
|
[Fexx]0(s)
|
→
|
[Cuxx]0(s)
|
+
|
Fe2+(aq)
|
|
Blue solution
|
|
Grey powder
|
|
Reddish
brown metal
|
|
Light green solution |
|